Formation of [Ni(III)(κ(1)-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)]- via CS2 insertion into nickel(III) hydride containing [Ni(III)(H)(P(o-C6H3-3-SiMe3-2-S)3)]-.
Inorg Chem
; 52(8): 4151-3, 2013 Apr 15.
Article
in En
| MEDLINE
| ID: mdl-23541028
ABSTRACT
Insertion of CS2 into the thermally unstable nickel(III) hydride [PPN][Ni(H)(P(o-C6H3-3-SiMe3-2-S)3)] (1), freshly prepared from the reaction of [PPN][Ni(OC6H5)P(C6H3-3-SiMe3-2-S)3] and 4,4,5,5-tetramethyl-1,3,2-dioxaborolane (HBpin; pin = OCMe2CMe2O) in tetrahydrofuran at -80 °C via a metathesis reaction, readily affords [PPN][Ni(III)(κ(1)-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)] (2) featuring a κ(1)-S2CH moiety.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
Carbon Disulfide
/
Cupriavidus necator
/
Coordination Complexes
/
Hydrogenase
/
Nickel
Language:
En
Journal:
Inorg Chem
Year:
2013
Document type:
Article
Affiliation country:
Taiwan