Chiral phosphoric acid-catalyzed oxidative kinetic resolution of indolines based on transfer hydrogenation to imines.
J Am Chem Soc
; 135(32): 11740-3, 2013 Aug 14.
Article
in En
| MEDLINE
| ID: mdl-23865933
ABSTRACT
The oxidative kinetic resolution of 2-substituted indoline derivatives was achieved by hydrogen transfer to imines by means of a chiral phosphoric acid catalyst. The oxidative kinetic resolution was applicable to racemic alkyl- or aryl-substituted indolines, and the remaining indolines were obtained in good yields with excellent enantioselectivities.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
Phosphoric Acids
/
Imines
/
Indoles
Language:
En
Journal:
J Am Chem Soc
Year:
2013
Document type:
Article
Affiliation country:
Japan