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Stereochemical lability of azatitanacyclopropanes: dynamic kinetic resolution in reductive cross-coupling reactions with allylic alcohols.
Yang, Dexi; Micalizio, Glenn C.
Affiliation
  • Yang D; Department of Chemistry, Dartmouth College, Hanover, NH 03755, USA. glenn.c.micalizio@dartmouth.edu.
Chem Commun (Camb) ; 49(78): 8857-9, 2013 Oct 09.
Article in En | MEDLINE | ID: mdl-23963189
ABSTRACT
Azatitanacyclopropanes (titanaziridines) are shown to be stereochemically labile under reaction conditions for reductive cross-coupling. This fundamental property has been employed to realize highly selective asymmetric coupling reactions with allylic alcohols that proceed by dynamic kinetic resolution.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Aza Compounds / Aziridines / Propanols / Cyclopropanes Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2013 Document type: Article Affiliation country: United States
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Aza Compounds / Aziridines / Propanols / Cyclopropanes Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2013 Document type: Article Affiliation country: United States