Importance of co-donor field strength in the preparation of tetradentate α-diimine nickel hydrosilylation catalysts.
Dalton Trans
; 42(41): 14689-92, 2013 Oct 01.
Article
in En
| MEDLINE
| ID: mdl-24030659
ABSTRACT
Although bis(α-diimine)Ni complexes were prepared when amine-substituted chelates were added to Ni(COD)2, the incorporation of strong-field phosphine donors allowed the isolation of (κ(4)-N,N,P,P-DI)Ni hydrosilylation catalysts. The crystallographic investigation of two different (κ(4)-N,N,P,P-DI)Ni compounds revealed that the geometry about nickel influences the observed degree of α-diimine reduction.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Dalton Trans
Journal subject:
QUIMICA
Year:
2013
Document type:
Article
Affiliation country:
United States
Publication country:
ENGLAND
/
ESCOCIA
/
GB
/
GREAT BRITAIN
/
INGLATERRA
/
REINO UNIDO
/
SCOTLAND
/
UK
/
UNITED KINGDOM