Static secondary ionization mass spectrometry detection of cyclohexylamine on soil surfaces exposed to laboratory air.
J Am Soc Mass Spectrom
; 7(2): 168-72, 1996 Feb.
Article
in En
| MEDLINE
| ID: mdl-24203238
ABSTRACT
Cyclohexylamine (CHA) is a common indoor air contaminant, which rapidly adsorbs to aluminosilicate soil samples. Static secondary ion mass spectrometry was used to study soil samples exposed to both CHA and CHA-d 11, and the results showed (1) abundant [M+H](+) and fragment ions that originated from CHA, (2) an initial concentration of CHA equivalent to approximately 0.2 monolayer, and (3) a possible exchange reaction where excess CHA-d 11 displaces CHA originally adsorbed to the surface. CHA was not removed from the surface by prolonged exposure to vacuum conditions (5×10(-7) torr), which indicates that CHA strongly adsorbs to aluminosilicate surfaces and should be expected as an endogenous surface contaminant where the chemical is used as a corrosion inhibitor.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Type of study:
Diagnostic_studies
Language:
En
Journal:
J Am Soc Mass Spectrom
Year:
1996
Document type:
Article
Affiliation country:
Indonesia