Electrochemical flow-reactor for expedient synthesis of copper-N-heterocyclic carbene complexes.
Chem Commun (Camb)
; 51(7): 1282-4, 2015 Jan 25.
Article
in En
| MEDLINE
| ID: mdl-25476754
ABSTRACT
An electrochemical flow-cell for highly efficient and selective generation of Cu(I)-N-heterocyclic carbene complexes under neutral and ambient conditions is reported. The feasibility of the flow-cell is demonstrated through the electrochemical synthesis of [Cu(IMes)Cl] and subsequent in situ flow directly into hydrosilylation reactions, with equal efficiency to the purified catalyst.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
Organometallic Compounds
/
Copper
/
Heterocyclic Compounds
/
Methane
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2015
Document type:
Article
Affiliation country:
United kingdom