Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe-amine complexes.
Chem Commun (Camb)
; 51(25): 5355-8, 2015 Mar 28.
Article
in En
| MEDLINE
| ID: mdl-25482568
The synthesis and structural characterization is reported for [Fe(dien)2][FeSe2]2 and [Fe(tren)][FeSe2]2, two new mixed-valence compounds that contain infinite ∞(1)(FeSe2) tetrahedral chains separated by Fe-amine complexes. The inter- and intra-chain magnetic interactions can be controlled by changing the denticity of the amine while preserving the general structural motif.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2015
Document type:
Article
Affiliation country:
United States
Country of publication:
United kingdom