A solid-state effect responsible for an organic quintet state at room temperature and ambient pressure.
Adv Mater
; 27(10): 1718-23, 2015 Mar 11.
Article
in En
| MEDLINE
| ID: mdl-25619560
ABSTRACT
A stable organic diradicaloid with an intermolecular quintet at room temperature as a polycrystalline solid is studied. The conclusion is supported by the observation of the ΔMs = ±2 forbidden transition, electron spin resonance (ESR) simulations, and density functional theory (DFT) calculations. In addition, the molecule, as the active component of a device, is an outstanding near-infrared photodetector with detectivity over 10(11) cm Hz(1/2) W(-1) at 1200 nm.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Adv Mater
Journal subject:
BIOFISICA
/
QUIMICA
Year:
2015
Document type:
Article
Affiliation country:
United States