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The stereostructure of candicidin D.
Szwarc, Katarzyna; Szczeblewski, Pawel; Sowinski, Pawel; Borowski, Edward; Pawlak, Jan.
Affiliation
  • Szwarc K; Department of Pharmaceutical Technology and Biochemistry, Gdansk University of Technology, Gdansk, Poland.
  • Szczeblewski P; Department of Pharmaceutical Technology and Biochemistry, Gdansk University of Technology, Gdansk, Poland.
  • Sowinski P; Department of Pharmaceutical Technology and Biochemistry, Gdansk University of Technology, Gdansk, Poland.
  • Borowski E; Department of Pharmaceutical Technology and Biochemistry, Gdansk University of Technology, Gdansk, Poland.
  • Pawlak J; Department of Pharmaceutical Technology and Biochemistry, Gdansk University of Technology, Gdansk, Poland.
J Antibiot (Tokyo) ; 68(8): 504-10, 2015 Aug.
Article in En | MEDLINE | ID: mdl-25712395
ABSTRACT
The candicidin D stereostructure was established based on NMR studies including DQF-COSY, ROESY, HSQC and HMBC experiments. The relative configurations of the candicidin D stereogenic centers were assigned as the following 9R*, 11S*, 13S*, 15R*, 17S*, 18R*, 19S*, 21R*, 36S*, 37R*, 38S*, 40S* and 41S*. The geometry of the heptaene chromophore was defined as 22E, 24E, 26Z, 28Z, 30E, 32E and 34E.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Candicidin / Molecular Structure Limits: Humans Language: En Journal: J Antibiot (Tokyo) Year: 2015 Document type: Article Affiliation country: Poland
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Candicidin / Molecular Structure Limits: Humans Language: En Journal: J Antibiot (Tokyo) Year: 2015 Document type: Article Affiliation country: Poland