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The first case of actinide triple helices: pH-dependent structural evolution and kinetically-controlled transformation of two supramolecular conformational isomers.
An, Shu-wen; Mei, Lei; Wang, Cong-zhi; Xia, Chuan-qin; Chai, Zhi-fang; Shi, Wei-qun.
Affiliation
  • An SW; College of Chemistry, Sichuan University, Chengdu 610064, China. xiachqin@163.com.
Chem Commun (Camb) ; 51(43): 8978-81, 2015 May 28.
Article in En | MEDLINE | ID: mdl-25931132
The first actinide triple helices, including two supramolecular conformational isomers of uranium(VI), have been synthesized with the aid of a flexible V-shaped ligand and a rigid aromatic base. The isomers exhibit an intriguing pH-dependent structural evolution and a kinetically-controlled transformation via a novel conformational rearrangement of the organic base.
Subject(s)

Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Actinoid Series Elements Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2015 Document type: Article Affiliation country: China Country of publication: United kingdom

Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Actinoid Series Elements Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2015 Document type: Article Affiliation country: China Country of publication: United kingdom