Halomethyl-cobalt(bis-acetylacetonate) for the controlled synthesis of functional polymers.
Chem Commun (Camb)
; 51(76): 14334-7, 2015 Oct 01.
Article
in En
| MEDLINE
| ID: mdl-26273709
ABSTRACT
Novel organocobalt complexes featuring weak C-CoL2 bonds (L = acetylacetonate) are prepared and used as sources of halomethyl radicals. They permit the precision synthesis of α-halide functionalized and telechelic polymers in organic media or in water. Substitution of halide by azide allows derivatization of polymers using the CuAAC click reaction.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2015
Document type:
Article
Affiliation country:
Belgium