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Microporous Polymers from a Carbazole-Based Triptycene Monomer: Synthesis and Their Applications for Gas Uptake.
Zhai, Tian-Long; Tan, Liangxiao; Luo, Yi; Liu, Jun-Min; Tan, Bien; Yang, Xiang-Liang; Xu, Hui-Bi; Zhang, Chun.
Affiliation
  • Zhai TL; Key Laboratory of Molecular Biophysics of the Ministry of Education, College of Life Science and Technology, Huazhong University of Science and Technology, National Engineering Research Center for Nanomedicine, Hubei, 430074, China.
  • Tan L; School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Hubei, 430074, China.
  • Luo Y; Key Laboratory of Molecular Biophysics of the Ministry of Education, College of Life Science and Technology, Huazhong University of Science and Technology, National Engineering Research Center for Nanomedicine, Hubei, 430074, China.
  • Liu JM; School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275, China. liujunm@mail.sysu.edu.cn.
  • Tan B; School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Hubei, 430074, China. bien.tan@hust.edu.cn.
  • Yang XL; Key Laboratory of Molecular Biophysics of the Ministry of Education, College of Life Science and Technology, Huazhong University of Science and Technology, National Engineering Research Center for Nanomedicine, Hubei, 430074, China.
  • Xu HB; Key Laboratory of Molecular Biophysics of the Ministry of Education, College of Life Science and Technology, Huazhong University of Science and Technology, National Engineering Research Center for Nanomedicine, Hubei, 430074, China.
  • Zhang C; Key Laboratory of Molecular Biophysics of the Ministry of Education, College of Life Science and Technology, Huazhong University of Science and Technology, National Engineering Research Center for Nanomedicine, Hubei, 430074, China. chunzhang@hust.edu.cn.
Chem Asian J ; 11(2): 294-8, 2016 Jan.
Article in En | MEDLINE | ID: mdl-26563911
ABSTRACT
Two kinds of novel organic microporous polymers TCPs (TCP-A and TCP-B) were prepared by two cost-effective synthetic strategies from the monomer of tricarbazolyltriptycene (TCT). Their structure and properties were characterized by FT-IR, solid (13) C NMR, powder XRD, SEM, TEM, and gas absorption measurements. TCP-B displayed a high surface area (1469 m(2) g(-1) ) and excellent H2 storage (1.70 wt % at 1 bar/77 K) and CO2 uptake abilities (16.1 wt % at 1 bar/273 K), which makes it a promising material for potential application in gas storage.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Asian J Year: 2016 Document type: Article Affiliation country: China
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Asian J Year: 2016 Document type: Article Affiliation country: China