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Synthesis of Chiral Vicinal Diamines by Silver(I)-Catalyzed Enantioselective Aminolysis of N-Tosylaziridines.
Chai, Zhuo; Yang, Pei-Jun; Zhang, Hu; Wang, Shaowu; Yang, Gaosheng.
Affiliation
  • Chai Z; Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, 1 East Beijing Road, Wuhu, Anhui, 241000, China.
  • Yang PJ; Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, 1 East Beijing Road, Wuhu, Anhui, 241000, China.
  • Zhang H; Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, 1 East Beijing Road, Wuhu, Anhui, 241000, China.
  • Wang S; Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, 1 East Beijing Road, Wuhu, Anhui, 241000, China.
  • Yang G; State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, P.R. China.
Angew Chem Int Ed Engl ; 56(2): 650-654, 2017 01 09.
Article in En | MEDLINE | ID: mdl-27918132
ABSTRACT
The kinetic resolution of 2-aryl-N-tosylaziridines and the asymmetric desymmetrization of meso-N-tosylaziridines by ring openings with various primary and secondary anilines, and aliphatic amines as nucleophile have been realized by using a single silver(I)/chiral diphosphine complex as catalyst for the first time. The simple starting materials, broad scope, and easy scalability render this protocol a practical way to chiral vicinal diamine derivatives.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Type of study: Guideline Language: En Journal: Angew Chem Int Ed Engl Year: 2017 Document type: Article Affiliation country: China
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Full text: 1 Collection: 01-internacional Database: MEDLINE Type of study: Guideline Language: En Journal: Angew Chem Int Ed Engl Year: 2017 Document type: Article Affiliation country: China