Light-Controlled Release and Uptake of Zinc Ions in Solution by a Photochromic Terthiazole-Based Ligand.
Chem Asian J
; 12(8): 853-859, 2017 Apr 18.
Article
in En
| MEDLINE
| ID: mdl-28328111
ABSTRACT
We have synthesized and fully characterized a photochromic zinc complex with a terphenylthiazole-based ligand with a salen-like cavity. The solution stability of the complex was found to be greatly dependent on the state of the photochromic ligand and an interesting photo-triggered release and uptake of zinc ions was found as well as monitored by its fluorescence. The contrasting stability difference of the zinc complex between its two isomeric states was rationalized by DFT calculations.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Asian J
Year:
2017
Document type:
Article
Affiliation country:
France