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Synthesis of Phenylpropanoids via Matsuda-Heck Coupling of Arene Diazonium Salts.
Schmidt, Bernd; Wolf, Felix.
Affiliation
  • Schmidt B; Universitaet Potsdam, Institut fuer Chemie , Karl-Liebknecht-Straße 24-25, D-14476 Potsdam-Golm, Germany.
  • Wolf F; Universitaet Potsdam, Institut fuer Chemie , Karl-Liebknecht-Straße 24-25, D-14476 Potsdam-Golm, Germany.
J Org Chem ; 82(8): 4386-4395, 2017 04 21.
Article in En | MEDLINE | ID: mdl-28394127
ABSTRACT
The Pd-catalyzed Heck-type coupling (Matsuda-Heck reaction) of electron rich arene diazonium salts with electron deficient olefins has been exploited for the synthesis of phenylpropanoid natural products. Examples described herein are the naturally occurring benzofurans methyl wutaifuranate, wutaifuranol, wutaifuranal, their 7-methoxy derivatives, and the O-prenylated natural products boropinols A and C.

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Org Chem Year: 2017 Document type: Article Affiliation country: Germany

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Org Chem Year: 2017 Document type: Article Affiliation country: Germany