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Vanadium Hydroxide Cluster Ions in the Gas Phase: Bond-Forming Reactions of Doubly-Charged Negative Ions by SO2 -Promoted V-O Activation.
Troiani, Anna; Rosi, Marzio; Garzoli, Stefania; Salvitti, Chiara; de Petris, Giulia.
Affiliation
  • Troiani A; Dipartimento di Chimica e Tecnologie del Farmaco, Sapienza University of Rome, P.le Aldo Moro 5, 00185, Roma, Italy.
  • Rosi M; Dipartimento di Ingegneria Civile e Ambientale, Università di Perugia and ISTM-CNR, Via Duranti 93, 06125, Perugia, Italy.
  • Garzoli S; Dipartimento di Chimica e Tecnologie del Farmaco, Sapienza University of Rome, P.le Aldo Moro 5, 00185, Roma, Italy.
  • Salvitti C; Dipartimento di Chimica e Tecnologie del Farmaco, Sapienza University of Rome, P.le Aldo Moro 5, 00185, Roma, Italy.
  • de Petris G; Dipartimento di Chimica e Tecnologie del Farmaco, Sapienza University of Rome, P.le Aldo Moro 5, 00185, Roma, Italy.
Chemistry ; 23(49): 11752-11756, 2017 Sep 04.
Article in En | MEDLINE | ID: mdl-28632305
ABSTRACT
The gas-phase reactivity of doubly-charged vanadium hydroxides anions with SO2 has been studied by experimental and computational methods. The obtained results highlight the role of sulfur dioxide in promoting unprecedented bond-forming reactions, which produce singly-charged products by breaking the Vx Oy skeleton or a terminal V-O bond.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chemistry Journal subject: QUIMICA Year: 2017 Document type: Article Affiliation country: Italy
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chemistry Journal subject: QUIMICA Year: 2017 Document type: Article Affiliation country: Italy