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Visible-Light-Promoted Oxidative Amidation of Bromoalkynes with Anilines: An Approach to α-Ketoamides.
Ni, Ke; Meng, Ling-Guo; Wang, Kuai; Wang, Lei.
Affiliation
  • Ni K; Department of Chemistry , Huaibei Normal University , Huaibei , Anhui 235000 , P. R. China.
  • Meng LG; Department of Chemistry , Huaibei Normal University , Huaibei , Anhui 235000 , P. R. China.
  • Wang K; Department of Chemistry , Huaibei Normal University , Huaibei , Anhui 235000 , P. R. China.
  • Wang L; Department of Chemistry , Huaibei Normal University , Huaibei , Anhui 235000 , P. R. China.
Org Lett ; 20(8): 2245-2248, 2018 04 20.
Article in En | MEDLINE | ID: mdl-29600860
ABSTRACT
A convenient and practical synthetic route to α-ketoamides from bromoalkynes and anilines through phototriggered organic transformations via a C-N cross-coupling and an oxidation of C≡C was developed. The reaction could be furnished without an external photocatalyst at ambient conditions, and a wide range of α-ketoamides were obtained in good yields.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2018 Document type: Article
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2018 Document type: Article