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Highly effective electrosynthesis of hydrogen peroxide from oxygen on a redox-active cationic covalent triazine network.
Peng, Lan-Zhen; Liu, Pei; Cheng, Qing-Qing; Hu, Wen-Jing; Liu, Yahu A; Li, Jiu-Sheng; Jiang, Biao; Jia, Xue-Shun; Yang, Hui; Wen, Ke.
Affiliation
  • Peng LZ; Department of Chemistry, Shanghai University, Shanghai 200444, China.
Chem Commun (Camb) ; 54(35): 4433-4436, 2018 Apr 26.
Article in En | MEDLINE | ID: mdl-29651495
Direct electrosynthesis of hydrogen peroxide (H2O2) by oxygen reduction is a green and safe strategy to replace the traditional anthraquinone process. Herein, we have designed a two-dimensional redox-active cationic covalent triazine network to be used directly as a cost-effective metal-free electrocatalyst for the oxygen reduction reaction (ORR) to form H2O2. Such a dicationic 2D polymer possesses a porous structure with pore diameters of 2-10 nm and a total N content of 13.3 wt%. The electron paramagnetic resonance experiment confirms the reduction of a viologen-based polymer to radical cations and the subsequent generation of superoxygen radicals. The radical characteristics and high N content within this polymer are the essential for the efficient ORR via a two-electron pathway. As a result, the present electrocatalyst exhibits a high ORR activity and excellent H2O2 selectivity (∼85%), thus providing a feasible possibility of designing highly selective metal-free electrocatalysts for electrocatalytic production of H2O2 from O2.

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2018 Document type: Article Affiliation country: China Country of publication: United kingdom

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2018 Document type: Article Affiliation country: China Country of publication: United kingdom