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Terarylenes as Photoactivatable Hydride Donors.
Martin, Colin J; Minamide, Miho; Dela Cruz Calupitan, Jan Patrick; Asato, Ryosuke; Kuno, Jumpei; Nakashima, Takuya; Rapenne, Gwénaël; Kawai, Tsuyoshi.
Affiliation
  • Martin CJ; Graduate School of Science and Technology , Nara Institute of Science and Technology (NAIST) , 8916-5 Takayama-cho , Ikoma , Nara 630-0192 , Japan.
  • Minamide M; International Collaborative Laboratory for Supraphotoactive Systems, NAIST-CEMES, CNRS , UPR 8011, 29 rue J. Marvig , Toulouse F-31055 , France.
  • Dela Cruz Calupitan JP; Graduate School of Science and Technology , Nara Institute of Science and Technology (NAIST) , 8916-5 Takayama-cho , Ikoma , Nara 630-0192 , Japan.
  • Asato R; Graduate School of Science and Technology , Nara Institute of Science and Technology (NAIST) , 8916-5 Takayama-cho , Ikoma , Nara 630-0192 , Japan.
  • Kuno J; International Collaborative Laboratory for Supraphotoactive Systems, NAIST-CEMES, CNRS , UPR 8011, 29 rue J. Marvig , Toulouse F-31055 , France.
  • Nakashima T; CEMES , Université de Toulouse, CNRS , Toulouse F-31055 , France.
  • Rapenne G; Graduate School of Science and Technology , Nara Institute of Science and Technology (NAIST) , 8916-5 Takayama-cho , Ikoma , Nara 630-0192 , Japan.
  • Kawai T; Graduate School of Science and Technology , Nara Institute of Science and Technology (NAIST) , 8916-5 Takayama-cho , Ikoma , Nara 630-0192 , Japan.
J Org Chem ; 83(22): 13700-13706, 2018 11 16.
Article in En | MEDLINE | ID: mdl-30295030
ABSTRACT
Terarylene frameworks containing benzothiazole as a photoprecursor of hydride donors are presented. We here report on two new scaffolds along with their photoreactivity in solution. Through use of selected external oxidants, the photogeneration of hydride donors is monitored using UV-visible, NMR, and TEM methods. As a proof-of-concept, photogeneration of hydride in the presence of Ag+ gave rise to the formation of Ag nanoparticles.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Org Chem Year: 2018 Document type: Article Affiliation country: Japan
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Org Chem Year: 2018 Document type: Article Affiliation country: Japan