Terarylenes as Photoactivatable Hydride Donors.
J Org Chem
; 83(22): 13700-13706, 2018 11 16.
Article
in En
| MEDLINE
| ID: mdl-30295030
ABSTRACT
Terarylene frameworks containing benzothiazole as a photoprecursor of hydride donors are presented. We here report on two new scaffolds along with their photoreactivity in solution. Through use of selected external oxidants, the photogeneration of hydride donors is monitored using UV-visible, NMR, and TEM methods. As a proof-of-concept, photogeneration of hydride in the presence of Ag+ gave rise to the formation of Ag nanoparticles.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
J Org Chem
Year:
2018
Document type:
Article
Affiliation country:
Japan