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Irradiation-Induced Cobaloxime-Catalyzed C-H Monofluoroalkylation of Styrenes at Room Temperature.
Tang, Wei-Ke; Xu, Zhuo-Wei; Xu, Jun; Tang, Fei; Li, Xiao-Xuan; Dai, Jian-Jun; Xu, Hua-Jian; Feng, Yi-Si.
Affiliation
  • Tang WK; Anhui Province Key Laboratory of Advance Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering , Hefei University of Technology , Hefei 230009 , P. R. China.
  • Xu ZW; Anhui Province Key Laboratory of Advance Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering , Hefei University of Technology , Hefei 230009 , P. R. China.
  • Xu J; School of Food and Biological Engineering , Hefei University of Technology , Hefei 230009 , P. R. China.
  • Tang F; Anhui Province Key Laboratory of Advance Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering , Hefei University of Technology , Hefei 230009 , P. R. China.
  • Li XX; Anhui Province Key Laboratory of Advance Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering , Hefei University of Technology , Hefei 230009 , P. R. China.
  • Dai JJ; School of Food and Biological Engineering , Hefei University of Technology , Hefei 230009 , P. R. China.
  • Xu HJ; Anhui Province Key Laboratory of Advance Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering , Hefei University of Technology , Hefei 230009 , P. R. China.
  • Feng YS; School of Food and Biological Engineering , Hefei University of Technology , Hefei 230009 , P. R. China.
Org Lett ; 21(1): 196-200, 2019 01 04.
Article in En | MEDLINE | ID: mdl-30550293
ABSTRACT
A cobaloxime-catalyzed photochemical synthesis of allyl monofluorides from styrenes is described herein. This method is characterized by mild reaction conditions, low-cost catalyst, and broad substrate scope. Furthermore, this convenient method will provide a facile synthesis toward novel monofluoroalkylated natural product and pharmaceutical derivatives. Mechanistic investigations indicate that a monofluoroalkyl radical is involved in the catalytic cycle.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2019 Document type: Article
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2019 Document type: Article