Preparation and Application of Conductive Polyaniline-Coated Thermally Expandable Microspheres.
Polymers (Basel)
; 11(1)2018 Dec 24.
Article
in En
| MEDLINE
| ID: mdl-30960006
ABSTRACT
The thermally expandable microspheres (TEMs) were prepared through suspension polymerization with acrylonitrile (AN), methyl methacrylate (MMA) and methyl acrylate (MA) as the main monomers. Simultaneously, iso-pentane, n-hexane, iso-octane and other low-boiling hydrocarbons were prepared as blowing agents under two conditions, including high-pressure nitrogen and atmospheric conditions. The above physical foaming microspheres have a core-shell structure and excellent foaming effects. A layer of polyaniline (PANI) was deposited on the surface of the prepared TEMs by emulsion polymerization to obtain conductive and heat-expandable microspheres. Afterwards, the foaming ink was prepared by mixing the conductive TEMs and water-based ink. Finally, a conductive three-dimensional picture was obtained by screen-printing technology. This paper specifically focuses on the effects of particle size, morphology and the thermal expansion properties of the microspheres. The present research methods expect to obtain microspheres with a high foaming ratio, uniform particle size and antistatic properties, which may be applied to physical foaming ink.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Polymers (Basel)
Year:
2018
Document type:
Article
Affiliation country:
China