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Threshold photoelectron spectrum of the CH2OO Criegee intermediate.
Chicharro, David V; Poullain, Sonia Marggi; Bañares, Luis; Hrodmarsson, Helgi Rafn; García, Gustavo A; Loison, Jean-Christophe.
Affiliation
  • Chicharro DV; Departamento de Química Física, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040 Madrid, Spain.
Phys Chem Chem Phys ; 21(24): 12763-12766, 2019 Jun 28.
Article in En | MEDLINE | ID: mdl-31179449
ABSTRACT
We present the photoelectron spectroscopy of the simplest Criegee intermediate, CH2OO, close to the first ionization energy. Comparison with existing theoretical data yields the experimental adiabatic ionization energy and provides a benchmark for theoretical studies on larger Criegee intermediates, which play an important role in the ozonolysis of alkenes.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Phys Chem Chem Phys Journal subject: BIOFISICA / QUIMICA Year: 2019 Document type: Article Affiliation country: Spain
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Phys Chem Chem Phys Journal subject: BIOFISICA / QUIMICA Year: 2019 Document type: Article Affiliation country: Spain