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A ruthenium bisoxazoline complex as a photoredox catalyst for nitro compound reduction under visible light.
Jia, Wei-Guo; Cheng, Ming-Xia; Gao, Li-Li; Tan, Siu Min; Wang, Chao; Liu, Xiaogang; Lee, Richmond.
Affiliation
  • Jia WG; The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials (State Key Laboratory Cultivation Base), College of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241002, China. wgjiasy@mail.ahnu.edu.cn.
  • Cheng MX; The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials (State Key Laboratory Cultivation Base), College of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241002, China. wgjiasy@mail.ahnu.edu.cn.
  • Gao LL; The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials (State Key Laboratory Cultivation Base), College of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241002, China. wgjiasy@mail.ahnu.edu.cn.
  • Tan SM; Science and Mathematics Cluster, Singapore University of Technology and Design, 8 Somapah Rd, Singapore 487372. richmond_lee@sutd.edu.sg.
  • Wang C; Science and Mathematics Cluster, Singapore University of Technology and Design, 8 Somapah Rd, Singapore 487372. richmond_lee@sutd.edu.sg.
  • Liu X; Science and Mathematics Cluster, Singapore University of Technology and Design, 8 Somapah Rd, Singapore 487372. richmond_lee@sutd.edu.sg.
  • Lee R; Science and Mathematics Cluster, Singapore University of Technology and Design, 8 Somapah Rd, Singapore 487372. richmond_lee@sutd.edu.sg.
Dalton Trans ; 48(27): 9949-9953, 2019 Jul 21.
Article in En | MEDLINE | ID: mdl-31237588
ABSTRACT
An unreported ruthenium(ii) complex containing bisoxazoline ligands has been synthesized and characterized. To test the catalytic ability of the ruthenium complex, the synthesis of anilines from nitro compounds in the presence of a mild reducing agent sodium borohydride and visible light has been developed. Mechanistic studies involving the experiment and DFT calculations suggest that the reaction could involve a radical pathway with the assistance of a photoredox catalyst.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2019 Document type: Article Affiliation country: China
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2019 Document type: Article Affiliation country: China