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Porphyrinic Silver Cluster Assembled Material for Simultaneous Capture and Photocatalysis of Mustard-Gas Simulant.
Cao, Man; Pang, Rui; Wang, Qian-You; Han, Zhen; Wang, Zhao-Yang; Dong, Xi-Yan; Li, Shun-Fang; Zang, Shuang-Quan; Mak, Thomas C W.
Affiliation
  • Cao M; College of Chemistry and Molecular Engineering , Zhengzhou University , Zhengzhou 450001 , China.
  • Pang R; International Laboratory for Quantum Functional Materials of Henan and School of Physics and Engineering , Zhengzhou University , Zhengzhou 450001 , China.
  • Wang QY; College of Chemistry and Molecular Engineering , Zhengzhou University , Zhengzhou 450001 , China.
  • Han Z; College of Chemistry and Molecular Engineering , Zhengzhou University , Zhengzhou 450001 , China.
  • Wang ZY; College of Chemistry and Molecular Engineering , Zhengzhou University , Zhengzhou 450001 , China.
  • Dong XY; College of Chemistry and Molecular Engineering , Zhengzhou University , Zhengzhou 450001 , China.
  • Li SF; International Laboratory for Quantum Functional Materials of Henan and School of Physics and Engineering , Zhengzhou University , Zhengzhou 450001 , China.
  • Zang SQ; College of Chemistry and Molecular Engineering , Zhengzhou University , Zhengzhou 450001 , China.
  • Mak TCW; College of Chemistry and Molecular Engineering , Zhengzhou University , Zhengzhou 450001 , China.
J Am Chem Soc ; 141(37): 14505-14509, 2019 Sep 18.
Article in En | MEDLINE | ID: mdl-31423775
ABSTRACT
Silver cluster-assembled materials (SCAMs), by virtue of their tunable structure, accessible surface area and excellent stability, hold great promise as highly efficient catalysts. Herein, we report a new SCAM [Ag12(StBu)6(CF3COO)3(TPyP)]n (denoted as Ag12TPyP) composed of a Ag12 chalcogenolate cluster core stabilized by porphyrinic ligands. Ag12TPyP showed superior sulfur mustard simulant (2-chloroethyl ethyl sulfide, CEES) degradation efficiency and achieved a half lifetime (t1/2) of 1.5 min with 100% selectivity. The experimental results demonstrated that synergistic effects between the silver cluster and photosensitizer ligand promote the efficiency of the generation of singlet oxygen (1O2), which accelerates the decontamination rate. Additionally, benefiting from strong affinity between the silver cluster and CEES, Ag12TPyP exhibits a CEES uptake of 74.2 mg g-1. This work demonstrates that SCAMs offer a new route to the rational design of novel materials for the detoxification of mustard gas.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Am Chem Soc Year: 2019 Document type: Article Affiliation country: China
Fulltext
Add to My VHL
Print
XML
PubMed Links
Search on Google

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Am Chem Soc Year: 2019 Document type: Article Affiliation country: China