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Harnessing enzyme plasticity for the synthesis of oxygenated sesquiterpenoids.
Demiray, Melodi; Miller, David J; Allemann, Rudolf K.
Affiliation
  • Demiray M; School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT. United Kingdom.
  • Miller DJ; School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT. United Kingdom.
  • Allemann RK; School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT. United Kingdom.
Beilstein J Org Chem ; 15: 2184-2190, 2019.
Article in En | MEDLINE | ID: mdl-31598175
ABSTRACT
8-Methoxy-γ-humulene, (E)-8-methoxy-ß-farnesene, 12-methoxy-ß-sesquiphellandrene and 12-methoxyzingiberene can be synthesised in amorphadiene synthase-catalysed reactions from 8- and 12-methoxyfarnesyl diphosphates due to the highly plastic yet tightly controlled carbocationic chemistry of this sesquiterpene cyclase.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Beilstein J Org Chem Year: 2019 Document type: Article
Fulltext
Add to My VHL
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XML
PubMed Links
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Beilstein J Org Chem Year: 2019 Document type: Article