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Crystal structure of tetra-kis-(tetra-hydro-furan-κO)bis-(tri-fluoro-methane-sulfonato-κO)iron(II).
Riemersma, Charl F; Monkcom, Emily C; Klein Gebbink, Robertus J M; Lutz, Martin.
Affiliation
  • Riemersma CF; Organic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Faculty of Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, The Netherlands.
  • Monkcom EC; Organic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Faculty of Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, The Netherlands.
  • Klein Gebbink RJM; Organic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Faculty of Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, The Netherlands.
  • Lutz M; Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Faculty of Science, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands.
Acta Crystallogr E Crystallogr Commun ; 75(Pt 10): 1548-1551, 2019 Oct 01.
Article in En | MEDLINE | ID: mdl-31636992
The title compound, [Fe(CF3SO3)2(C4H8O)4], is octa-hedral with two tri-fluoro-methane-sulfonate ligands in trans positions and four tetra-hydro-furane mol-ecules in the equatorial plane. By the conformation of the ligands the complex is chiral in the crystal packing. The compound crystallizes in the Sohncke space group P212121 and is enanti-omerically pure. The packing of the mol-ecules is determined by weak C-H⋯O hydrogen bonds. The crystal studied was refined as a two-component inversion twin.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Acta Crystallogr E Crystallogr Commun Year: 2019 Document type: Article Affiliation country: Netherlands Country of publication: United kingdom
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Acta Crystallogr E Crystallogr Commun Year: 2019 Document type: Article Affiliation country: Netherlands Country of publication: United kingdom