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Circularly polarised luminescence from planar-chiral Phanephos/Tb(iii)(hfa)3 hybrid luminophores.
Taniguchi, Ayano; Hara, Nobuyuki; Shizuma, Motohiro; Tajima, Nobuo; Fujiki, Michiya; Imai, Yoshitane.
Affiliation
  • Taniguchi A; Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan. y-imai@apch.kindai.ac.jp.
  • Hara N; Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan. y-imai@apch.kindai.ac.jp.
  • Shizuma M; Department of Biochemistry, Osaka Research Institute of Industrial Science and Technology, Joto-ku, Osaka 536-8553, Japan.
  • Tajima N; Computational Materials Science Center, National Institute for Materials Science 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan.
  • Fujiki M; Division of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara 630-0192, Japan.
  • Imai Y; Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan. y-imai@apch.kindai.ac.jp.
Photochem Photobiol Sci ; 18(12): 2859-2864, 2019 Dec 01.
Article in En | MEDLINE | ID: mdl-31687727
ABSTRACT
Planar-chiral Phanephos, containing the coordinatable P(iii), formed P(iii)/Tb(iii)(hfa)3 hybrid luminophores that successfully emitted characteristic circularly polarised luminescence (CPL) due to 5D4→7F5 transitions in solution. On the other hand, BINAP, containing P(iii)[double bond, length as m-dash]O as axially chiral ligand, exhibited no detectable CPL with Tb(iii)(hfa)3.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Photochem Photobiol Sci Journal subject: BIOLOGIA / QUIMICA Year: 2019 Document type: Article Affiliation country: Japan Publication country: ENGLAND / ESCOCIA / GB / GREAT BRITAIN / INGLATERRA / REINO UNIDO / SCOTLAND / UK / UNITED KINGDOM
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Photochem Photobiol Sci Journal subject: BIOLOGIA / QUIMICA Year: 2019 Document type: Article Affiliation country: Japan Publication country: ENGLAND / ESCOCIA / GB / GREAT BRITAIN / INGLATERRA / REINO UNIDO / SCOTLAND / UK / UNITED KINGDOM