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Highly Selective Synthesis of Tetrahydronaphthaleno[60]fullerenes via Fullerene-Cation-Mediated Intramolecular Cyclization.
Yang, Xiao-Yu; Lin, Hao-Sheng; Matsuo, Yutaka.
Affiliation
  • Yang XY; Hefei National Laboratory for Physical Sciences at the Microscale , University of Science and Technology of China , 96 Jinzhai Road , Hefei , Anhui 230026 , China.
  • Lin HS; Department of Mechanical Engineering, School of Engineering , The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku , Tokyo 113-8656 , Japan.
  • Matsuo Y; Hefei National Laboratory for Physical Sciences at the Microscale , University of Science and Technology of China , 96 Jinzhai Road , Hefei , Anhui 230026 , China.
J Org Chem ; 84(24): 16314-16322, 2019 Dec 20.
Article in En | MEDLINE | ID: mdl-31742406
ABSTRACT
A high-yielding protocol to construct six-membered carbon rings on fullerene is presented. This methodology with in situ fullerene-cation-mediated intramolecular cyclization provides high selectivity and efficient access to six-membered tetrahydronaphthaleno[60]fullerenes with a remarkable functional group tolerance and excellent yields. Furthermore, high solubilities of tetrahydronaphthaleno[60]fullerenes are reported.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Org Chem Year: 2019 Document type: Article Affiliation country: China
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Add to My VHL
Print
XML
PubMed Links
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Org Chem Year: 2019 Document type: Article Affiliation country: China