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A mixed-ligand strategy regulates thorium-based MOFs.
Huang, Zhi-Wei; Hu, Kong-Qiu; Mei, Lei; Kong, Xiang-He; Yu, Ji-Pan; Liu, Kang; Zeng, Li-Wen; Chai, Zhi-Fang; Shi, Wei-Qun.
Affiliation
  • Huang ZW; Laboratory of Nuclear Energy Chemistry. Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China.
Dalton Trans ; 49(4): 983-987, 2020 Jan 28.
Article in En | MEDLINE | ID: mdl-31904068
Two novel thorium-based organic frameworks (Th-IHEP-5 and Th-IHEP-6) were assembled from a hexanuclear thorium cluster, porphyrin derivative ligand and linear carboxylic acid ligands via a mixed-ligand strategy. As a stable heterogeneous catalyst, Th-IHEP-5 exhibited high photocatalytic activity for the oxidation of 2-chloroethyl ethyl sulfide (CEES) and the fixation of CO2. The good catalytic effect is attributed to the large conjugated system of porphyrin and the photosensitizer enhancing effects of bipyridine.

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2020 Document type: Article Affiliation country: China Country of publication: United kingdom

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2020 Document type: Article Affiliation country: China Country of publication: United kingdom