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Interfacial Synthesis of Electrically Conducting Palladium Bis(dithiolene) Complex Nanosheet.
Pal, Tigmansu; Kambe, Tetsuya; Kusamoto, Tetsuro; Foo, Maw Lin; Matsuoka, Ryota; Sakamoto, Ryota; Nishihara, Hiroshi.
Affiliation
  • Pal T; Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan).
  • Kambe T; Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan).
  • Kusamoto T; Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan).
  • Foo ML; Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan).
  • Matsuoka R; Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan).
  • Sakamoto R; Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan).
  • Nishihara H; Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan).
Chempluschem ; 80(8): 1255-1258, 2015 Aug.
Article in En | MEDLINE | ID: mdl-31973302
The synthesis of palladium bis(dithiolene) complex nanosheets (PdDt) possessing a kagome-type lattice structure was performed via interfacial reaction between metal salt in aqueous phase and dithiolato ligand in organic phase. The PdDt nanosheets were characterised by AFM, STM, TEM revealing flat and sheet-like morphology; IR, UV spectroscopy show the corresponding coordination connectivity between metal and ligand, followed by powder X-ray diffraction and SAED, which determined nanosheets to be structurally similar to previously reported nickel bis(dithiolene) complex nanosheets NiDt.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chempluschem Year: 2015 Document type: Article Country of publication: Germany
Fulltext
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chempluschem Year: 2015 Document type: Article Country of publication: Germany