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Taming the Reactivity of Phosphiranium Salts: Site-Selective C-Centered Ring Opening for Direct Synthesis of Phosphinoethylamines.
Gasnot, Julien; Botella, Clément; Comesse, Sébastien; Lakhdar, Sami; Alayrac, Carole; Gaumont, Annie-Claude; Dalla, Vincent; Taillier, Catherine.
Affiliation
  • Gasnot J; Normandie Univ., URCOM, UNIHAVRE, FR 3032, EA 3221, 25 rue Philippe Lebon, BP 540, 76058, Le Havre, France.
  • Botella C; Normandie Univ., URCOM, UNIHAVRE, FR 3032, EA 3221, 25 rue Philippe Lebon, BP 540, 76058, Le Havre, France.
  • Comesse S; Normandie Univ., URCOM, UNIHAVRE, FR 3032, EA 3221, 25 rue Philippe Lebon, BP 540, 76058, Le Havre, France.
  • Lakhdar S; Normandie Univ., LCMT, ENSICAEN, UNICAEN, CNRS, 6, Boulevard Marechal Juin, 14000, Caen, France.
  • Alayrac C; Normandie Univ., LCMT, ENSICAEN, UNICAEN, CNRS, 6, Boulevard Marechal Juin, 14000, Caen, France.
  • Gaumont AC; Normandie Univ., LCMT, ENSICAEN, UNICAEN, CNRS, 6, Boulevard Marechal Juin, 14000, Caen, France.
  • Dalla V; Normandie Univ., URCOM, UNIHAVRE, FR 3032, EA 3221, 25 rue Philippe Lebon, BP 540, 76058, Le Havre, France.
  • Taillier C; Normandie Univ., URCOM, UNIHAVRE, FR 3032, EA 3221, 25 rue Philippe Lebon, BP 540, 76058, Le Havre, France.
Angew Chem Int Ed Engl ; 59(29): 11769-11773, 2020 Jul 13.
Article in En | MEDLINE | ID: mdl-32240563
ABSTRACT
Advances in the field of phosphorus chemistry are documented, by revealing the synthetic utility of previously underutilized quaternary phosphiranium salts (QPrS) as three-chain-atom electrophilic building blocks. Notably, control of their challenging C-centered electrophilicity is disclosed with an expedient synthesis of tertiary ß-anilino phosphines as a proof-of-concept.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Angew Chem Int Ed Engl Year: 2020 Document type: Article Affiliation country: France
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Angew Chem Int Ed Engl Year: 2020 Document type: Article Affiliation country: France