Ir-catalyzed selective dehydrogenative cross-coupling of aryls with o-carboranes via a mixed directing-group strategy.
Chem Commun (Camb)
; 56(51): 7001-7004, 2020 Jun 25.
Article
in En
| MEDLINE
| ID: mdl-32441711
ABSTRACT
An efficient Ir-catalyzed selective B-H/C-H dehydrocoupling between o-carboranes and (hetero)aryls has been achieved based on a mixed directing-group strategy, leading to a wide variety of carborane-(hetero)arene combinations. Control experiments indicate that aryl C-H activation proceeds preferentially over the B-H one. Thus, a plausible reaction pathway for dehydrogenative cross-coupling is proposed after the characterization of a key intermediate.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2020
Document type:
Article