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Ni-Catalyzed Denitrogenative Cross-Coupling of Benzotriazinones and Cyclopropanols: An Easy Access to Functionalized ß-Aryl Ketones.
Li, Jincan; Zheng, Yan; Huang, Mingxian; Li, Wanfang.
Affiliation
  • Li J; College of Science, University of Shanghai for Science and Technology, Shanghai 200093, China.
  • Zheng Y; College of Science, University of Shanghai for Science and Technology, Shanghai 200093, China.
  • Huang M; College of Science, University of Shanghai for Science and Technology, Shanghai 200093, China.
  • Li W; College of Science, University of Shanghai for Science and Technology, Shanghai 200093, China.
Org Lett ; 22(13): 5020-5024, 2020 Jul 02.
Article in En | MEDLINE | ID: mdl-32525323
ABSTRACT
A novel Ni-catalyzed denitrogenative cross-coupling between benzotriazinones and cyclopropanols is reported herein. This neoteric reactivity allows for the convenient synthesis of ß-(o-amido)aryl ketones from readily available starting materials with good yields (up to 93%) and general substrate scope.

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2020 Document type: Article Affiliation country: China

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2020 Document type: Article Affiliation country: China