An experimental and first-principle investigation of the Ca-substitution effect on P3-type layered NaxCoO2.
Chem Commun (Camb)
; 56(58): 8107-8110, 2020 Jul 21.
Article
in En
| MEDLINE
| ID: mdl-32555815
ABSTRACT
We experimentally and computationally investigated the Ca substitution effect on the electrochemical performance of P3-NaxCoO2. The cycle performance of Ca-substituted NaxCa0.04CoO2 was effectively improved due to its better crystallinity retention after charging. Our DFT calculations suggested that the presence of Ca2+ ions in Na sites kinetically mitigates phase transition.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2020
Document type:
Article
Affiliation country:
Japan