Morphology and properties of thermoplastic starch blended with biodegradable polyester and filled with halloysite nanoclay.
Carbohydr Polym
; 242: 116392, 2020 Aug 15.
Article
in En
| MEDLINE
| ID: mdl-32564842
ABSTRACT
The incorporation of halloysite clay nanotubes (HNTs) into thermoplastic starch/poly(butylene adipate-co-terephthalate) (TPS/PBAT) blends has been investigated with the aim of improving the compatibility and properties of the matrix. TPS/PBAT/HNTs nano-biocomposites with different TPS/PBAT weight fractions and HNTs contents were elaborated using a melt blending process, and their morphology and properties were investigated. The TPS80/PBAT20 and TPS20/PBAT80 blends exhibited dispersed phases of small droplets of PBAT or TPS, respectively, whereas the TPS50/PBAT50 blend presented a more homogeneous structure. Elongation at break of the TPS/PBAT/HNTs biocomposites with 5 wt% of HNTs significantly increased with increasing PBAT proportion, i.e., 6.5 %, 41.3 %, and 351.5 % for the composites based on TPS80/PBAT20, TPS50/PBAT50, and TPS20/PBAT80, respectively. The incorporation of 5 wt% of HNTs improved compatibility and increased Young's modulus of the TPS80/PBAT20, TPS50/PBAT50, and TPS20/PBAT80 blends approx. 350 %, 142 %, and 18 %, respectively. These results demonstrate that HNTs are promising nanofillers to improve properties of TPS-based blends.
Key words
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
Polyesters
/
Starch
/
Biocompatible Materials
/
Clay
/
Nanoparticles
Language:
En
Journal:
Carbohydr Polym
Year:
2020
Document type:
Article
Affiliation country:
Thailand