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Formation of disinfection by-products in a UV-activated mixed chlorine/chloramine system.
Liu, Zhi; Xu, Bin; Zhang, Tian-Yang; Hu, Chen-Yan; Tang, Yu-Lin; Dong, Zheng-Yu; Cao, Tong-Cheng; El-Din, Mohamed Gamal.
Affiliation
  • Liu Z; State Key Laboratory of Pollution Control and Resource Reuse, Key Laboratory of Yangtze Water Environment, Ministry of Education, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, PR China; Shanghai Institute of Pollution Control and Ecological Security, Shanghai
  • Xu B; State Key Laboratory of Pollution Control and Resource Reuse, Key Laboratory of Yangtze Water Environment, Ministry of Education, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, PR China; Shanghai Institute of Pollution Control and Ecological Security, Shanghai
  • Zhang TY; State Key Laboratory of Pollution Control and Resource Reuse, Key Laboratory of Yangtze Water Environment, Ministry of Education, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, PR China; Shanghai Institute of Pollution Control and Ecological Security, Shanghai
  • Hu CY; College of Environmental and Chemical Engineering, Shanghai University of Electric Power, Shanghai 200090, PR China.
  • Tang YL; State Key Laboratory of Pollution Control and Resource Reuse, Key Laboratory of Yangtze Water Environment, Ministry of Education, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, PR China; Shanghai Institute of Pollution Control and Ecological Security, Shanghai
  • Dong ZY; State Key Laboratory of Pollution Control and Resource Reuse, Key Laboratory of Yangtze Water Environment, Ministry of Education, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, PR China; Shanghai Institute of Pollution Control and Ecological Security, Shanghai
  • Cao TC; School of Chemical Science and Engineering, Key Laboratory of Road and Traffic Engineering of Ministry of Education, Tongji University, Shanghai 200092, PR China.
  • El-Din MG; Department of Civil and Environmental Engineering, University of Alberta, Edmonton AB T6G1H9, Canada.
J Hazard Mater ; 407: 124373, 2021 04 05.
Article in En | MEDLINE | ID: mdl-33153788
ABSTRACT
In recent years, ultraviolet (UV) irradiation coupled with chlor(am)ination process is ubiquitous in secondary water supply systems in many cities of China. However, the disinfection by-products (DBPs) formation in a UV-activated mixed chlorine/chloramine system (MCCS) still remains unclear. In this study, the DBPs formation in a UV-activated MCCS was systematically investigated, considering influencing factors including the mass ratios of free chlorine to NH2Cl, UV irradiation, pH values, NOM types, Br- concentration and toxicity of the DBPs. Results indicated that DBPs formation decreased remarkably as mass ratio of free chlorine to NH2Cl changed from 50 to 05. The DBPs formation in humic acid (HA)-containing water was the highest, followed by those in fulvic acid (FA) and algal organic matter (AOM). Besides, better control of the DBP-related calculated toxicity can be achieved in acidic conditions regardless of the UV irradiation. Furthermore, in the presence of Br-, a significant reduction of DBPs formation could be achieved in a UV-activated MCCS. The findings also demonstrated that DBPs formation in real water can be effectively reduced at high UV fluence in a MCCS.
Key words

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Hazard Mater Journal subject: SAUDE AMBIENTAL Year: 2021 Document type: Article

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Hazard Mater Journal subject: SAUDE AMBIENTAL Year: 2021 Document type: Article