Synthesis of redox-active fluorinated 5-hydroxytryptophans as molecular reporters for biological electron transfer.
Chem Commun (Camb)
; 57(25): 3107-3110, 2021 Mar 28.
Article
in En
| MEDLINE
| ID: mdl-33626126
ABSTRACT
Fluorinated 5-hydroxytryptophans (Fn-5HOWs) were synthesized in gram scale quantities and incorporated into a ß-hairpin peptide and the protein azurin. The redox-active Fn-5HOWs exhibit unique radical spectroscopic signatures that expand the function of as probes for biological electron transfer.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
5-Hydroxytryptophan
/
Halogenation
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2021
Document type:
Article
Affiliation country:
United States