Melt-Spun Fibers from Bio-Based Polyester-Fiber Structure Development in High-Speed Melt Spinning of Poly(ethylene 2,5-furandicarboxylate) (PEF).
Materials (Basel)
; 14(5)2021 Mar 02.
Article
in En
| MEDLINE
| ID: mdl-33801526
ABSTRACT
Poly(ethylene 2,5-furandicarboxylate) (PEF) is regarded as a bio-based alternative or complementary polyester for the widely used fossil resource-based polyester, poly(ethylene terephthalate) (PET). High-speed melt spinning of PEF of low and high molecular weight (L-PEF, H-PEF) was conducted, and the structure and properties of the resultant as-spun fibers were investigated. The occurrence of orientation-induced crystallization was confirmed for the H-PEF at the take-up velocity of 6.0 km/min, the highest speed for producing PET fibers in the industry. Molecular orientation and crystallinity of the as-spun fibers increased with the increase of take-up velocity, where the H-PEF fibers always showed a higher degree of structural development than the L-PEF fibers. The tensile modulus of the high-speed spun H-PEF fibers was relatively low at 5 GPa, whereas a sufficiently high tensile strength of approximately 500 MPa was measured. These values are adequately high for the application in the general semi-engineering fiber field.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Materials (Basel)
Year:
2021
Document type:
Article
Affiliation country:
Japan