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N5 +: A Novel Homoleptic Polynitrogen Ion as a High Energy Density Material.
Christe, Karl O; Wilson, William W; Sheehy, Jeffrey A; Boatz, Jerry A.
Affiliation
  • Christe KO; Propulsion Sciences and Advanced Concepts Division, Air Force Research Laboratory (AFRL/PRS), Edwards Air Force Base, CA 93524 (USA), Fax: (+1) 661-275-5471 (and) Loker Hydrocarbon Research Institute, University of Southern California, Los Angeles, CA 90089 (USA).
  • Wilson WW; Propulsion Sciences and Advanced Concepts Division, Air Force Research Laboratory (AFRL/PRS), Edwards Air Force Base, CA 93524 (USA), Fax: (+1) 661-275-5471 (and) Loker Hydrocarbon Research Institute, University of Southern California, Los Angeles, CA 90089 (USA).
  • Sheehy JA; Propulsion Sciences and Advanced Concepts Division, Air Force Research Laboratory (AFRL/PRS), Edwards Air Force Base, CA 93524 (USA), Fax: (+1) 661-275-5471 (and) Loker Hydrocarbon Research Institute, University of Southern California, Los Angeles, CA 90089 (USA).
  • Boatz JA; Propulsion Sciences and Advanced Concepts Division, Air Force Research Laboratory (AFRL/PRS), Edwards Air Force Base, CA 93524 (USA), Fax: (+1) 661-275-5471 (and) Loker Hydrocarbon Research Institute, University of Southern California, Los Angeles, CA 90089 (USA).
Angew Chem Int Ed Engl ; 38(13-14): 2004-2009, 1999 Jul 12.
Article in En | MEDLINE | ID: mdl-34182671
ABSTRACT
Only the third known example of a homoleptic polynitrogen species besides N2 and N3 -, the N5 + ion possesses surprising stability and can be isolated on a macroscopic scale as its AsF6 - salt. The assigment of the C2v-symmetric structure (shown schematically) predicted by calculations was supported by IR and Raman as well as 14N and 15N NMR spectroscopic studies of the isotopically labeled product.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Angew Chem Int Ed Engl Year: 1999 Document type: Article
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Angew Chem Int Ed Engl Year: 1999 Document type: Article