Diorganyl diselenides: a powerful tool for the construction of selenium containing scaffolds.
Dalton Trans
; 50(37): 12764-12790, 2021 Sep 28.
Article
in En
| MEDLINE
| ID: mdl-34581339
ABSTRACT
Organoselenium compounds find versatile applications in organic synthesis, materials synthesis, and ligand chemistry. Organoselenium heterocycles are widely studied agents with diverse applications in various biological processes. This review highlights the recent progress in the synthesis of selenium heterocycles using diorganyl diselenides with keen attention on green synthetic approaches, scopes, C-H selanylation, the mechanisms of different reactions and insights into the formation of metal complexes. The C-H selanylation using diorganyl diselenides with different catalysts, bases, transition metals, iodine salts, NIS, hypervalent iodine, and other reagents is summarised. Finally, the diverse binding modes of bis(2/4-pyridyl)diselenide with different metal complexes are also summarised.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Dalton Trans
Journal subject:
QUIMICA
Year:
2021
Document type:
Article
Affiliation country:
Japan