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Enhanced Sieving of C2-Hydrocarbon from Methane by Fluoro-Functionalization of In-MOF with Robust Stability.
Guo, Yan; Liang, Chen; Zhang, Chengcheng C; Ferrando-Soria, Jesús; Gao, Yu; Yang, Jiahui H; Liu, Xiangyu Y; Pardo, Emilio.
Affiliation
  • Guo Y; State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan, 750021, P. R. China.
  • Liang C; State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan, 750021, P. R. China.
  • Zhang CC; State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan, 750021, P. R. China.
  • Ferrando-Soria J; Departamento de Química Inorgánica, Instituto de Ciencia Molecular (ICMOL), Universidad de Valencia, Paterna, 46980, Valencia, Spain.
  • Gao Y; State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan, 750021, P. R. China.
  • Yang JH; State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan, 750021, P. R. China.
  • Liu XY; State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan, 750021, P. R. China.
  • Pardo E; Departamento de Química Inorgánica, Instituto de Ciencia Molecular (ICMOL), Universidad de Valencia, Paterna, 46980, Valencia, Spain.
Chem Asian J ; 17(1): e202101220, 2022 Jan 03.
Article in En | MEDLINE | ID: mdl-34758095
ABSTRACT
Developing efficient adsorbent materials is crucial for adsorption and separation to realize the purification of energy source and raw chemicals. Here, we report a novel and robust 3D In-based MOF built up with fluorine-functionalized ligands, QMOF-2F, with improved separation properties of C2-light hydrocarbons over methane at room temperature respect isoreticular non-fluorinated MOF. QMOF-2F shows a remarkable chemical stability in different solvents, including water, and pH (2-12). DFT calculations support the key role of fluorine-functionalization on the improved performance of QMOF-2F.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Asian J Year: 2022 Document type: Article
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Asian J Year: 2022 Document type: Article