Advances on the Merger of Electrochemistry and Transition Metal Catalysis for Organic Synthesis.
Chem Rev
; 122(3): 3180-3218, 2022 02 09.
Article
in En
| MEDLINE
| ID: mdl-34797053
ABSTRACT
Synthetic organic electrosynthesis has grown in the past few decades by achieving many valuable transformations for synthetic chemists. Although electrocatalysis has been popular for improving selectivity and efficiency in a wide variety of energy-related applications, in the last two decades, there has been much interest in electrocatalysis to develop conceptually novel transformations, selective functionalization, and sustainable reactions. This review discusses recent advances in the combination of electrochemistry and homogeneous transition-metal catalysis for organic synthesis. The enabling transformations, synthetic applications, and mechanistic studies are presented alongside advantages as well as future directions to address the challenges of metal-catalyzed electrosynthesis.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
Transition Elements
Language:
En
Journal:
Chem Rev
Year:
2022
Document type:
Article
Affiliation country:
United States