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The O/S heteroatom effects of covalent triazine frameworks for photocatalytic hydrogen evolution.
Liu, Manying; Yang, Kangni; Li, Zhenyang; Fan, Erchuang; Fu, Huafeng; Zhang, Like; Zhang, Yange; Zheng, Zhi.
Affiliation
  • Liu M; Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, College of Chemical and Materials Engineering, Xuchang University, Henan 461000, China. zhangyg@xcu.edu.cn.
  • Yang K; School of Civil Engineering and Communication, North China University of Water Resources and Electric Power, Zhengzhou 450046, China.
  • Li Z; School of Civil Engineering and Communication, North China University of Water Resources and Electric Power, Zhengzhou 450046, China.
  • Fan E; School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China.
  • Fu H; Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, College of Chemical and Materials Engineering, Xuchang University, Henan 461000, China. zhangyg@xcu.edu.cn.
  • Zhang L; Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, College of Chemical and Materials Engineering, Xuchang University, Henan 461000, China. zhangyg@xcu.edu.cn.
  • Zhang Y; Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, College of Chemical and Materials Engineering, Xuchang University, Henan 461000, China. zhangyg@xcu.edu.cn.
  • Zheng Z; Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, College of Chemical and Materials Engineering, Xuchang University, Henan 461000, China. zhangyg@xcu.edu.cn.
Chem Commun (Camb) ; 58(1): 92-95, 2021 Dec 21.
Article in En | MEDLINE | ID: mdl-34874023
ABSTRACT
S/O heterocyclic covalent triazine frameworks (CTFs i.e., CTF-7 and CTF-8) were synthesized using thiophene and furan as building blocks, respectively. The hydrogen evolution rate of CTF-7 is 7430 µmol g-1 h-1, which is about 5.6 times that of CTF-8. Due to their low electronegativity, sulfur heteroatoms are more favorable for charge separation than oxygen heteroatoms in CTFs. This work provides a guiding principle for the design of high efficiency photocatalyst structures.

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2021 Document type: Article Affiliation country: China

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2021 Document type: Article Affiliation country: China