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Utilization of BODIPY-based redox events to manipulate the Lewis acidity of fluorescent boranes.
Thompson, Brena L; Kieffer, Ian A; Heiden, Zachariah M.
Affiliation
  • Thompson BL; Department of Chemistry, Washington State University, Pullman, WA 99164, USA. zachariah.heiden@wsu.edu.
  • Kieffer IA; Department of Chemistry, Washington State University, Pullman, WA 99164, USA. zachariah.heiden@wsu.edu.
  • Heiden ZM; Department of Chemistry, Washington State University, Pullman, WA 99164, USA. zachariah.heiden@wsu.edu.
Chem Commun (Camb) ; 58(16): 2646-2649, 2022 Feb 22.
Article in En | MEDLINE | ID: mdl-34981098
ABSTRACT
This report describes the implementation of a 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dye into the ligand framework of a borane. The redox-active nature of the BODIPY dye is utilized to generate a family of molecular boranes that are capable of exhibiting tunable Lewis acidities through BODIPY-based redox events.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2022 Document type: Article Affiliation country: United States
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2022 Document type: Article Affiliation country: United States