Unraveling the reactivity of a cationic iminoborane: avenues to unusual boron cations.
Chem Sci
; 13(8): 2303-2309, 2022 Feb 23.
Article
in En
| MEDLINE
| ID: mdl-35310477
ABSTRACT
A cationic terminal iminoborane [Mes*N[triple bond, length as m-dash]B â IPr2Me2][AlBr4] (3+[AlBr4]-) (Mes* = 2,4,6-tri-tert-butylphenyl and IPr2Me2 = 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene) has been synthesized and characterized. The employment of an aryl group and N-heterocyclic carbene (NHC) ligand enables 3+[AlBr4]- to exhibit both B-centered Lewis acidity and BN multiple bond reactivities, thus allowing for the construction of tri-coordinate boron cations 5+-12+. More importantly, initial reactions involving coordination, addition, and [2 + 3] cycloadditions have been observed for the cationic iminoborane, demonstrating the potential to build numerous organoboron species via several synthetic routes.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Sci
Year:
2022
Document type:
Article