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Ruthenium(iv) N-confused porphyrin µ-oxo-bridged dimers: acid-responsive molecular rotors.
Iwanaga, Osamu; Fukuyama, Kazuki; Mori, Shigeki; Song, Jun Tae; Ishihara, Tatsumi; Miyazaki, Takaaki; Ishida, Masatoshi; Furuta, Hiroyuki.
Affiliation
  • Iwanaga O; Department of Applied Chemistry, Graduate School of Engineering, Center for Molecular Systems, Kyushu University Fukuoka 819-0395 Japan t.miyazaki@fukuoka-u.ac.jp ishida.masatoshi.686@m.kyushu-u.ac.jp hfuruta@cstf.kyushu-u.ac.jp.
  • Fukuyama K; Department of Applied Chemistry, Graduate School of Engineering, Center for Molecular Systems, Kyushu University Fukuoka 819-0395 Japan t.miyazaki@fukuoka-u.ac.jp ishida.masatoshi.686@m.kyushu-u.ac.jp hfuruta@cstf.kyushu-u.ac.jp.
  • Mori S; Advanced Research Support Center, Ehime University Matsuyama 790-8577 Japan.
  • Song JT; Department of Applied Chemistry, Graduate School of Engineering, Center for Molecular Systems, Kyushu University Fukuoka 819-0395 Japan t.miyazaki@fukuoka-u.ac.jp ishida.masatoshi.686@m.kyushu-u.ac.jp hfuruta@cstf.kyushu-u.ac.jp.
  • Ishihara T; Department of Applied Chemistry, Graduate School of Engineering, Center for Molecular Systems, Kyushu University Fukuoka 819-0395 Japan t.miyazaki@fukuoka-u.ac.jp ishida.masatoshi.686@m.kyushu-u.ac.jp hfuruta@cstf.kyushu-u.ac.jp.
  • Miyazaki T; Department of Applied Chemistry, Graduate School of Engineering, Center for Molecular Systems, Kyushu University Fukuoka 819-0395 Japan t.miyazaki@fukuoka-u.ac.jp ishida.masatoshi.686@m.kyushu-u.ac.jp hfuruta@cstf.kyushu-u.ac.jp.
  • Ishida M; Department of Applied Chemistry, Graduate School of Engineering, Center for Molecular Systems, Kyushu University Fukuoka 819-0395 Japan t.miyazaki@fukuoka-u.ac.jp ishida.masatoshi.686@m.kyushu-u.ac.jp hfuruta@cstf.kyushu-u.ac.jp.
  • Furuta H; Department of Applied Chemistry, Graduate School of Engineering, Center for Molecular Systems, Kyushu University Fukuoka 819-0395 Japan t.miyazaki@fukuoka-u.ac.jp ishida.masatoshi.686@m.kyushu-u.ac.jp hfuruta@cstf.kyushu-u.ac.jp.
RSC Adv ; 11(40): 24575-24579, 2021 Jul 13.
Article in En | MEDLINE | ID: mdl-35481054
ABSTRACT
Ruthenium(iv) N-confused porphyrin µ-oxo-bridged complexes were synthesized via oxidative dimerization of a ruthenium(ii) N-confused porphyrin complex using 2,2,6,6-tetramethylpiperidine 1-oxyl. The deformed core planes in the dimers conferred a relatively high ring rotational barrier of ca. 16 kcal mol-1. Rotation of the complexes was controlled by protonating the peripheral nitrogen.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: RSC Adv Year: 2021 Document type: Article
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: RSC Adv Year: 2021 Document type: Article