Carbon vacancy-mediated exciton dissociation in Ti3C2Tx/g-C3N4 Schottky junctions for efficient photoreduction of CO2.

Earth-abundant g-C3N4 is a promising photocatalyst for CO2 reduction, but its practical application is severely limited by the excitonic effect of g-C3N4 derived from strong binding energy and lack of electron-enriched active sites. Herein, we design a novel 2D/2D Schottky junction photocatalysts comprising of Ti3C2Tx-modified defective g-C3N4 nanosheets with carbon vacancy (denoted as Ti3C2Tx/Vc-CN) by a self-assembly method. The carbon vacancies in g-C3N4 promote exciton dissociation into free charge, while the formed Schottky junctions between Ti3C2Tx and Vc-CN further enables a directional charge transfer, thus providing an electron-rich catalytic surface for the CO2 reduction. Thanks to the synergy of promoted exciton dissociation and directional electron transfer, the optimal 20% Ti3C2Tx/Vc-CN display a high CO evolution rate of 20.54 µmol·g-1·h-1 under visible light irradiation, which is 7.4 times higher than that of bare CN. This work highlights the synergy of the promoted exciton dissociation and directional electron transfer in the activity enhancement of photocatalytic CO2 reduction.