Gd(OH)F2: A Promising Cryogenic Magnetic Refrigerant.
J Am Chem Soc
; 144(30): 13787-13793, 2022 Aug 03.
Article
in En
| MEDLINE
| ID: mdl-35860923
ABSTRACT
Magnetic refrigerants with a large magnetocaloric effect (MCE) in a wide temperature range and low magnetic ordering temperature (To) in the sub-kelvin temperature region are not only crucial for adiabatic demagnetization refrigeration but also open up a broader parameter space for the optimal design of adiabatic demagnetization refrigerators. However, such magnetic refrigerants are extremely rare because they require magnetic materials to simultaneously satisfy three conditions low To, weak magnetic interaction, and high magnetic density. Here, we report the syntheses, heat capacities, and magnetic properties of Gd(OH)3-xFx (1 x = 1, 2 x ≈ 1.5, and 3 x = 2), demonstrating for the first time that the introduction of fluoride anions into antiferromagnetic Gd(OH)3 can effectively regulate its To. Significantly, 3 not only has a To of 0.5 K but also exhibits a large MCE in the temperature range from 0.5 to 4 K, representing the best magnetic refrigerant reported to date in the temperature range of 0.5-4 K from the viewpoint of the MCE.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
J Am Chem Soc
Year:
2022
Document type:
Article