BIAN-Aluminium-Catalysed Imine Hydrogenation.
ChemCatChem
; 14(15): e202200144, 2022 Aug 05.
Article
in En
| MEDLINE
| ID: mdl-36032039
ABSTRACT
Hydrogenations have been dominated by transition metal catalysis, while the use of more abundant and inexpensive main group metal catalysts has remained a great challenge. Here, a bimetallic Li/Al dihydride was successfully applied to catalytic hydrogenations of imines. The catalyst [(DippBIAN)Al(µ-H)2Li(OEt2)2] was easily prepared from the 2e-reduced BIAN derivative and LiAlH4.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
ChemCatChem
Year:
2022
Document type:
Article