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Photoredox Catalyzed Thioformylation of Terminal Alkynes Using Nitromethane as a Formyl Source.
Bhat, Muneer-Ul-Shafi; Ganie, Majid Ahmad; Rizvi, Masood Ahmad; Raheem, Shabnam; Shah, Bhahwal Ali.
Affiliation
  • Bhat MU; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India.
  • Ganie MA; Natural Product & Medicinal Chemistry, CSIR-Indian Institute of Integrative Medicine, Jammu 180001, India.
  • Rizvi MA; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India.
  • Raheem S; Natural Product & Medicinal Chemistry, CSIR-Indian Institute of Integrative Medicine, Jammu 180001, India.
  • Shah BA; Department of Chemistry, University of Kashmir, Srinagar 190006, India.
Org Lett ; 24(36): 6658-6663, 2022 Sep 16.
Article in En | MEDLINE | ID: mdl-36047745
ABSTRACT
A photoredox thioformylation of terminal alkynes using nitromethane as a formyl anion equivalent, thereby leading to the synthesis of (E)-1,2-difunctionalized acrylaldehyde, has been described. The current strategy introduces an adaptable aldehyde function across an alkyne and offers a new route to synthesizing α-alkyl/aryl aldehydes.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2022 Document type: Article Affiliation country: India
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Lett Journal subject: BIOQUIMICA Year: 2022 Document type: Article Affiliation country: India