Photoredox Catalyzed Thioformylation of Terminal Alkynes Using Nitromethane as a Formyl Source.
Org Lett
; 24(36): 6658-6663, 2022 Sep 16.
Article
in En
| MEDLINE
| ID: mdl-36047745
ABSTRACT
A photoredox thioformylation of terminal alkynes using nitromethane as a formyl anion equivalent, thereby leading to the synthesis of (E)-1,2-difunctionalized acrylaldehyde, has been described. The current strategy introduces an adaptable aldehyde function across an alkyne and offers a new route to synthesizing α-alkyl/aryl aldehydes.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Org Lett
Journal subject:
BIOQUIMICA
Year:
2022
Document type:
Article
Affiliation country:
India